Sputter Coater and Techniques
What is Sputter Coater
Sputter coater could be a compact or tabletop coating system that is ideally suitable for high-quality coating of non-conductive samples for scanning electron microscope imaging. Keeping the specimen dry and clean is a basic requirement before sputtering or evaporating coating. If necessary, the specimen and cathode are swapped and the surface is cleaned by glow discharge. After that, the specimen is recovered and then sputter coated. Iron, nickel, copper, and other sputtering targets are commonly used as cathode materials for this instrument, and sometimes electrode gold, platinum, palladium, indium, and other metals or carbon rope can also be used as “cathode materials”.
What is Sputtering Coating and How to define Sputter Coater
Sputtering is one of the PVD thin film preparation techniques, which are divided into four main categories: DC sputtering, RF sputtering, magnetron sputtering and reactive sputtering.
What does Sputtering Mean
Sputtering is the process of bombarding a target material with charged particles -> when the accelerated ions bombard the solid surface -> surface atomic collisions -> energy and momentum transfer occur -> causing the target material atoms to escape from the surface and deposit on the substrate material.
Sputtering is also a phenomenon in which atoms or molecules escape from the surface of target materials by bombarding with charged energy particles.
Since the sputtering process contains momentum conversion, the sputtered particles are directional.
What is Sputter Coating
Sputter coating appeared at the very beginning as simple DC diode sputtering. It has the advantage of just a simple device, but the DC dipole sputtering deposition rate is relatively low. It cannot be performed under the circumstance of low air pressure (<0.1 Pa) to maintain self-sustaining discharge. Disadvantages, such as the inability to sputter insulating materials, limit its application. If a hot cathode and an auxiliary anode are added to the DC dipole sputtering device, this constitutes DC triple sputtering. The hot electrons generated by the additional hot cathode and auxiliary anode enhance the ionization of the sputtering gas atoms, which makes sputtering possible even at low air pressure.
In addition, the sputtering voltage can be reduced which means sputtering is carried out at low air pressure and low voltage. At the same time, the discharge current of the sputtering coating is increased and can be controlled independently of the voltage. The addition of an electrode (grid-like) in front of the hot cathode constitutes a quadrupole sputtering device, which can stabilize the discharge. However, these devices have difficulties in obtaining plasma zones with high concentrations and low deposition rates, thus these tech are not widely used in industry.
What does Sputtered Mean
Sputtered can be used to obtain metal, alloy, or dielectric materials or films on the surface of other substrate material substance. It is suitable for manufacturing thin film integrated circuits, chip lead devices, semiconductor devices and so on.
What does Sputtering Process do
Sputtering process means that particles (ions or neutral atoms or molecules) of certain energy bombard the surface of a solid so that the atoms or molecules near the surface of the solid acquire a large enough energy to eventually escape from the surface of the solid.
Sputtering can only be performed under a certain vacuum pressure, so the sputtering process is also known as vacuum sputtering coating process.
Magnetron Sputtering Principles
Magnetron sputtering is a method to establish a magnetic field orthogonal to the electric field on the target surface to solve the problems of the low deposition rate of dipole sputtering and low plasma dissociation rate. So it has become one of the main methods in the coating industry.
Magnetron sputtering coating is a new type of physical vapor phase coating method. It uses an electron gun system to emit and focus electrons on the material to be coated so that the atoms sputtered out to follow the principle of momentum conversion and fly away from the material with high kinetic energy to deposit a film on the substrate. This coated material is called sputtering target. Sputtering targets include metals, alloys, ceramic compounds, etc.
Magnetron sputtering has the following characteristics compared to other coating technologies
1. Wide range of materials that can be prepared into targets, including alloys and ceramic materials, even almost all types of metals and compounds.
2. Co-sputtering of multiple targets under appropriate conditions, allowing the deposition of precisely proportioned and constant alloys.
3. The addition of oxygen, nitrogen, or other reactive gases to the sputtering discharge atmosphere allows the deposition of compound films forming the target material with gas molecules.
4. By precisely controlling the sputtering coating process, uniform and high-precision film thicknesses can be easily obtained.
5. The target material can be directly transformed from solid-state to a plasma state by ion sputtering tech, and the installation of sputtering targets is not limited to certain way, which is suitable for the design of a large volume coating chamber with multiple targets arrangement.
6. The characteristics of fast sputter coating, dense film, and good adhesion make it suitable for high volume and high-efficiency industrial production.
Sputtering Targets Requirements
The requirements of sputtering targets are higher than those of the traditional materials industry with general requirements like size, flatness, purity, impurity content, density, N/O/C/S, grain size, and defect control.
Sputtering targets also have high or special requirements, including surface roughness, resistance, grain size uniformity, composition and tissue uniformity, oxide content and size, magnetic permeability, ultra-high density & ultra-fine grains, etc.
Sputtering Targets are mainly used in the following fields
1. Electronics and information industry, including integrated circuits, information storage, liquid crystal display, laser memory, electronic control devices, etc.
2. Glass coating industry (sputter coating glass for example).
Wear-resistant and high-temperature corrosion-resistant industries.
3. high-grade decorative goods industry.
4. Other industries etc.
What is Sputtering Deposition
Sputter deposition is a method of sputtering atoms from a target by bombarding it with high-energy particles and depositing them on the surface of the substrate to form a thin film.
Advantages and Disadvantages of Sputtering Coating
1. Technically any substance can be sputtered, especially elements and compounds with high melting points and low vapor pressure. Solids of any shape, regardless of the substance such as metals, semiconductors, insulators, compounds, and mixtures, can be used as target materials. Since insulating materials and alloys such as oxides are not decomposed and fractionated when sputtered, they can be used to prepare thin films with similar components to the target material and alloy films with uniform components, and even superconducting films with complex compositions.
2. Good adhesion between the sputtered film and the substrate.
a. The energy of sputtered atoms is 1-2 orders of magnitude higher than that of evaporated atoms. Therefore, the high-energy particles are deposited on the substrate for energy conversion, generating higher thermal energy and enhancing the adhesion of the sputtered atoms to the substrate.
b. A portion of the sputtered atoms with high energy will produce different degrees of injection phenomena, forming a diffusion layer on the substrate where the sputtered atoms and the atoms of the substrate material are intermixed.
c. During the bombardment of sputtering particles, the substrate is always cleaned and activated in the plasma region, which removes the precipitated atoms that do not adhere well and purify and activates the substrate surface. Therefore, the adhesion of the sputtered film layer to the substrate is greatly enhanced.
3. In the sputter coating process, the phenomenon of evaporation source contamination, which cannot be avoided during vacuum vapor deposition, is not present. Therefore, the sputtering coating density is high, fewer pinholes and the purity of the film layer is high, too.
4. Since the film thickness can be controlled by controlling the target current during sputter coating. Therefore, the controllability of the film thickness of sputter coating and the reproducibility of the film thickness of multiple sputtering can effectively plate the predetermined thickness of the film.
5. Sputter coating can also obtain a uniform thickness film over a large area.
Disadvantage of Sputtering (Refers to Dipole Sputtering as well)
1. Complex sputtering equipment, requiring high (electrical) pressure devices.
2. Low sputtering deposition rate.
3. Rising temperature of the substrate is high and it is susceptible to impurity gases.
Sputter Coater for SEM
Electron Microscopies (SEM) is a versatile tool. Most of the time, it can be used to provide nanoscale information on various samples without sample preparation. And in some cases, it is necessary to use SEM in combination with an Ion sputter coater to obtain better SEM images.
How SEM Works and Principles
The sputtering technique of SEM gold coating can image almost all types of samples, ceramics, metals, alloys, semiconductors, polymers, biological samples, etc. However, some specific types of samples are more challenging and require the operator to perform additional sample preparation to collect high-quality images with the help of SEM gold spray. These additional steps include sputtering an extra conductive thin layer of material such as gold, silver, platinum, or chromium on the surface of the sample.
Disadvantages of SEM
Due to the ease of operation, there are a few concerns when using gold sputter coating. The only attention is that at the beginning, the operator needs to figure out the best parameters to get the best spraying results. However, after gold sputtering, the surface of the elements is no longer the original material and their liner information of them is lost.